Studies on Reactions of Some Homo and Heterobimetallic Lewis Acids With N,N’-Bis (Benzylidene) 1,2-Isopropylene Diamine (Bzdamp)

S. N. Shukla; Sadique Khan; N. UpadhYay; N. Manikpuri; S. K. Jain; A. Srivastava

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Studies on Reactions of Some Homo and Heterobimetallic Lewis Acids With N,N’-Bis (Benzylidene) 1,2-Isopropylene Diamine (Bzdamp)

S. N. Shukla¹, Sadique Khan², N. UpadhYay³, N. Manikpuri⁴, S. K. Jain⁴ and A. Srivastava⁵

¹Department of Chemistry. Government Autonomous Model Science College, Jabalpur -482 001 (India) ²Department of Chemistry, Government Autonomous Model Science SNS P.G. College, Shahdol - 484 001 (India) ³Department of Chemistry, Government Autonomous Model Science College, Rewa - 486 001 (India) ⁴Department of Chemistry, Government Nehur P.G. College, Burhar - 482 001 (India) ⁵Department of Chemistry, D.A.V. College, Kanpur (India)

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ABSTRACT:

Complex of MM’ (SCN)4 (M=CO2+, Ni2+, M’=Cd2+, Hg2+) with Schiff base derived from 1,2-diaminopropane with benzaldehyde, have been synthesized and characterized by elemental analyses, molar conductance, magnetic moment IR, electronic and 1H-NMMR studies. The softness parameters, DTEn¹= of the complex have also been calculated to derive the probable structures. The antifungal and antiviral activities have also been investigated . Complexes exhibit good antifungal activity at high concentrations which decreases rapidly at lower concentration and show very low insignificant antiviral activity.

KEYWORDS:

Schiff base; Homobimetallic; Heterobimetallic; Thiocyanate; Lewis acids