Catalytic Activities of Triphenylphosphine / Triphenylarsine Complexes of Ruthenium(Ii) With Mono Basic Bidentate Thiosemicarbazones

K. P. Balasubramanian; V. Chinnusamy

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Catalytic Activities of Triphenylphosphine / Triphenylarsine Complexes of Ruthenium(Ii) With Mono Basic Bidentate Thiosemicarbazones

K. P. Balasubramanian and V. Chinnusamy

Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore - 641 020 (India)

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ABSTRACT:

New hexa coordinated ruthenium(II) complexes of the type [RuCl(CO)(EPh3)2(L)] E=P or As; L= mono basic bidentate Schiff base derived from the condensation of thiosemicarbazide with p- tolualdehyde or p- anisaldehyde and o- chlorobenzaldehyde have been synthesized from the equimolar amounts of [RuHCl(CO)(PPh

KEYWORDS:

Bidentate thiosemicarbazones; ruthenium complexes; catalytic studies