Kinetics and Mechanism of Oxidation of Diethanolamine With Bi(V) in Hcio4- Hf Mixture

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Kinetics of oxidation of Diethanolamine (DEA) with Bi(V) fluoride complex has been studied in HCIO4-HF mixture. The reaction is first order with respect to each reactant. No effect of [H+], [HF] and [NaF] on the reaction rate observed, while ionic strength has-negative effect on the reaction rate. The mode of electron transfer from the substrate to the oxidant has been indicated via a bridged outer sphere mechanism.

Kinetics; Diethylamine; Bi(IV) ; HClO4- HF mixture