Synthesis and Characterisation of Rhodium (Iii) Complexes With Some N,N,S-Containing Ligands


Indranil Chakraborti* and H. C. Rai
Department of Chemistry, L. S. College, B.R.A. University, Muzaffarpur (India)

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ABSTRACT:

The synthesis of rhodium (III) complexes of seven thiosemicarbazones derived from 4-aminoantipyrine and various aryl aldehydes has been described. Elemental analyses, magnetic moments, IR and electronic spectral studies characterized the complexes. These complexes were found to have the compositions [Rh(Ligand)Cl3]. All the complexes are diamagnetic and are six-coordinated octahedral.

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