Mixed Ligand Complexes of Alkali Earth Metal Chelates of Organic Acids With Thiosalicylic Acid


R. N. Singh1, Sushma Kumari1, Anju K. Gupta1 and D. Prakash2

1P.G. Department of Chemistry, College of Commerce, Patna- 800 020 (India)

2Department of Chemistry, Patna University, Patna- 800 005 (India)

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ABSTRACT:

A of mixed ligand complexes of alkaline earth metal chelates of some organic acids with thioxalicylic acid having general formula ML2HL, where M = Mg, Ca, Sr or Ba, L = deprotonated 1N2N, 8HQ, ONP, DNP and HL= thiosalicylic acid have been synthesised and characterised by elemental analysis and IR spectral data. The IR spectra of these complexes indicate the coordination through S-atom of -SH group and O-atom of -COOH group of the thiosalicylic acid.

KEYWORDS:

thioxalicylic; IR spectra


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