Studies On Some Penta-Coordinate Complexes Of V(Iv) and Cu(Ii) With Imides and Amine Bases.

M. Saidul Islam¹* and M. Ashraful Alamb²

¹Department of Chemistry, University of Rajshahi, Rajshahi (Bangladesh) ²Department of Chemistry, BIT, Rajshahi (Bangladesh)

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ABSTRACT:

A of new mixed ligand Pentacoordinate complexes of oxovanadium (IV) and copper(II) containing imides and nitrogen containing amine bases have been synthesized. The complexes have the composition [M(P or S)2.L] and [M(P or S)2.L], where P=deprotonated phthalimide, S=deprotonated succinimide L=ethylenediamine (en) and L=diethylenetriamine (dien). All the complexes are found to be square pyrimidal.

KEYWORDS:

Penta-coordinate complexes; imides and amine bases