ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Copper(II) Carboxylate Containing Paddle Wheel Structure: Synthesis and Crystal Structure

Adnan M. Qadir

DOI : http://dx.doi.org/10.13005/ojc/330249


Abstract:

A dinuclear copper(II) complex of the type [Cu2(2-nb)4(MeOH)2] (2-nb = 2-nitrobenzoate) has been synthesized and characterized by single crystal X-ray diffraction method. The compound belongs to monoclinic space group P21/c with a = 19.9374(10) ٫ b = 21.1404(11) ٫c = 7.6533(4) Å, α = 90٫ β = 96.817(3)٫ γ = 90º٫ V = 3246.8(3) Å 3٫ Z = 4٫ F(000) = 1736.0.0٫ Dc = 1.774Mg/m3,  μ = 1.422 mm-1. The Cu(II) complex is a cocrystal containing two inorganic units. Each Cu(II) adopted square pyramidal geometry.

Keywords:

Paddle wheel; Nickel; Synthesis; Carboxylate

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